A duotone is made with two colors, black and a spot color. Here is how you can create a duotone photo in Photoshop. Your first step is to open your file in Photoshop. Then, create a grayscale image by going to Image > Mode > Grayscale. After you have a grayscale image go to Image > Mode > Duotone this will bring up your Duotone Options box and you can add your duotone Pantone color with the default black. I have chosen to work with the Pantone colors because in this course we have been working with Pantone colors. After choosing your colors you can now edit the duotone curve if you desire. Fifth and final step is to save your image. If you would like to continue to edit this photograph go to Image > mode > RGB then edit your photograph then go to File > Save As and save your file as EPS.

This image is my before image.
This image is my after image.
Source:
http://www.digital-photography-school.com/convert-duotones-photoshop
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